Just take the cap off before (or just after) starting. Make certain that he engine is cold before removal (if your neverous, place a towel over the cap and remove it.). It make take several minutes for the engine to warm up, but at some point within the first 10 mins or so, you should see the coolant start flowing past the cap opening. Then it should stop for a minute or two, then flow again....... This would be the thermostat opening and closing.
If nothing flows at all, start small work bigger, let it cool off and remove your thermostat. With no thermostat in place, you should have a constant flow........ FYI, easy way to check a thermostat, put it in a pan on the stove. As the water heats up, you'll see the spring open.
It's not likely that the coolant channels within the block are colgged........ But you can go to any Auto store and get a flush kit....But hold off on that just yet. Let's see of our coolant is at least moving.